MGX Minerals Inc. (“MGX” or the “Company”) (CSE:
XMG / FKT: 1MG / OTCQB: MGXMF) and
Highbury Energy
Inc. (“Highbury”) are pleased to report completion of a
comprehensive study analyzing beneficial gasification routes from
Petroleum Coke (“Petcoke”) to three products of value: Hydrogen, FT
Liquids and Fuel Gas. Each of these products has potential markets
in the oil sands and heavy oil industry. The report outlines a
variety and comparison of plant design parameters and a
Petcoke-to-Hydrogen process with metals concentration via
gasification, utilizing Highbury’s patented dual-bed gasification
technology, which requires no fine grinding or air separation unit.
The goal of ongoing joint research with Highbury is to develop fuel
source alternatives and concentrated battery metals by-products
including vanadium, nickel and cobalt, which can be seamlessly
integrated into existing refinery operations. The study is viewed
as positive and the project will now move to the demonstration
plant design phase and preliminary pre-feasibility analysis.
Metals in Pet Coke and AshPreviously released
assay results of Petcoke samples collected from stockpiles produced
from the Fort McMurray area mining and upgrading operation as well
as an Edmonton refinery are summarized below. Both samples
originated from Delayed Coking operations. Samples were obtained
and prepared by Highbury and metal contents analyzed by Acme Labs
of Vancouver, British Columbia using standard ICP analyses.
Ash ContentAsh content was determined by
weighing residues after burning coke samples of about 200 g in air
in a muffle oven over extended periods at 815°C. Table A indicates
the average ash content of 6 to 7 samples of each coke.
Table A. Ash Content of Coke
Samples |
Sample name |
Ash content (% wt.) |
No. of samples tested |
Upgrader Coke A |
2.73 ±0.09 |
6 |
Refinery Coke B |
0.32 ±0.04 |
7 |
Upgrader Coke A had about nine times as much ash as was in
Refinery Coke B.
Proximate AnalysesThe cokes contain over 95 %
organic (non-mineral) matter. Thermogravimetric analyses on 10 mg
quantities are shown below.
Table B. Proximate Analyses of Coke by the
Thermogravimetric Analyser Method |
Quantity (wt. %) |
Upgrader Coke A |
Refinery Coke B |
Volatile Matter |
8.9 |
10.0 |
Fixed Carbon |
86.9 |
86.3 |
Residues |
4.3 |
1.7 |
Residue refers to residual mineral matter left after the
thermogravimetric test. Except for the % Residue, the two cokes
have similar combustion properties.
Metals Analysis in the Coke SamplesLithium
borate fusion ICP-MS method measures 45 trace metal concentrations
in the coke. Results are expressed as (mg/kg) or ppmwt. Table C
lists concentrations of selected metals.
Table C. Selected Metal Concentrations in Coke
(mg Metal/kg Coke) |
Sample |
V |
Ni |
Cu |
Zr |
Co |
Au |
Ag |
Upgrader Coke A |
421 |
76.8 |
86.2 |
40.5 |
4.8 |
0.0011 |
<0.1 |
Refinery Coke B |
458 |
53.4 |
35.9 |
1.3 |
1.3 |
<0.0005 |
<0.1 |
Vanadium is the highest concentration of the 45 trace metals
detected in the coke samples.
Ash AnalysesAsh analysis was completed by
Bureau Veritas Commodities Canada Ltd. (“BV”) of Vancouver, British
Columbia using XRF method (XF701). Results are expressed as % wt.
in the ash as oxide. Sixteen elements as oxides, and LOI (loss on
ignition) are determined. The ash samples were prepared in
Highbury’s laboratory and sent to BV for analysis. The maximum %
the analysis method could accommodate was 10.0 % for V2O5;
therefore ash samples were diluted by mixing with other solids. In
the Highbury laboratory both Al2O3 and Fe2O3 were used.
Table D. Selected Species in the Ash of Each
Coke Type |
Species (wt. %) |
Upgrader Coke Ash A |
Refinery Coke Ash B |
Al2O3 |
27.7 |
9.8 |
SiO2 |
42.6 |
23.6 |
V2O5 |
6.6 |
45.1 |
Fe2O3 |
8.0 |
2.7 |
TiO2 |
5.7 |
0.7 |
K2O+MgO+CaO |
4.0 |
6.4 |
LOI |
0.0 |
4.3 |
SubTotal (wt.%) |
90.8 |
92.5 |
For Upgrader Coke A, the sum of Al2O3 +SiO2 is about 70 %. V2O5
is about 6.6%, according to the ash analyses. For Refinery Coke B,
the average % V2O5 in the ash is 45 %.
Table E. Trace Metals Concentration in Ash (mg
Metal/kg Ash) for Selected Species [Two Determinations
Average] |
Sample |
V |
Ni |
Cu |
Zr |
Co |
Au |
Ag |
Mo |
Upgrader Coke Ash A |
34600 |
740 |
130 |
1840 |
230 |
0.02 |
2.5 |
1405 |
Refinery Coke Ash B |
193000 |
177000 |
340 |
405 |
620 |
0.02 |
0.175 |
5000 |
Vanadium metal concentrations are 3.5 % wt. in Upgrader Coke Ash
A, and 19.3 % wt. in Refinery Coke Ash B, which is also enriched in
Nickel.
BackgroundPetcoke is a carbon material
by-product of the oil and gas industry that forms during the oil
refining process. As refineries have become more efficient at
processing extra heavy crude oils (bitumen) over the last two
decades, output of petcoke globally has risen significantly.
Because petcoke originates from heavier petroleum fractions, its
denser impurities such as metals and sulphur compounds are
concentrate in it.
The majority of Canadian petcoke output occurs in close
proximity to oil sand producing regions, where bitumen is upgraded
into synthetic crude oil. Specifically, the Province of Alberta is
known to host vast stockpiles of petcoke. According to the Alberta
Energy Regulator, petcoke inventories are estimated to have reached
106 million tonnes in 2016(1).
(1) Source: Alberta Energy Industry, Alberta Mineable Oil Sands
Plant Statistics
Research and DevelopmentDevelopment of the
detailed process will be spearheaded by Dr. Paul Watkinson, a
Professor Emeritus in the Department of Chemical and Biological
Engineering at the University of British Columbia and a co-founder
of Highbury. Dr. Watkinson is a published expert in the field of
gasification and oversaw early work on related oil sand
gasification in the early 1990’s. He is also a registered
Professional Engineer, Fellow of the Chemical Institute of Canada
and Fellow of the Canadian Academy of Engineering. Dr. Watkinson is
also an active participant in the Canadian Society for Chemical
Engineering as well as Engineering Conferences International. He
has received numerous awards for his research and has published
multiple articles in scientific journals on pilot-scale
investigations of conversion of carbonaceous solids, such as coal,
shale and biomass, into gaseous and liquid fuels.
N.I. 43-101Although authored by leading experts
in the field and significantly advancing research and development
of gasification and metals extraction, N.I. 43-101 does not
recognize a scoping study as a N.I. 43-101 Compliant Report. As
such MGX cannot release any economic projections whatsoever in
regard to metals extraction or associated gasification steps. As
Petcoke is widely available in very large quantities at low cost in
the Alberta Oil Sands it is unlikely MGX will complete an N.I.
43-101 Resource Estimate, which precludes a compliant Preliminary
Economic Assessment, Pre-feasibility Study or Feasibility Study
that would allow for the release of economic projections. It is
anticipated that a Pre-feasibility and Feasibility Study will be
completed for the plant design itself but not the Petcoke resource
as it will be purchased as needed and not owned or controlled by
MGX.
Qualified PersonAndris Kikauka (P. Geo.), Vice
President of Exploration for MGX Minerals, has reviewed and
approved the technical information in this press release. Mr.
Kikauka is a non-independent Qualified Person within the meaning of
National Instrument 43-101 Standards.
About Highbury EnergyHighbury Energy Inc. is an
innovative energy company dedicated to the development and
utilization of renewable energy resources through the procurement
and conversion of biomass. Highbury has developed a proprietary
dual-bed steam gasification technology and patented gas cleanup
system that converts biomass into high-grade synthesis or fuel gas.
This robust process produces a medium calorific value gas from most
types of organic matter, such as wood or agricultural wastes,
without need of tonnage oxygen. The cleaned synthesis gas can
readily replace natural gas in industrial kilns and furnaces in the
mineral, pulp & paper, glass, and cement industries.
Alternately, the syngas can fuel an internal combustion engine to
make electricity, with waste heat used for refrigeration, or
district heating. Syngas can also be converted to high value low
carbon liquid fuels such as diesel or jet fuel, or into chemicals
such as methanol or ethanol.
About MGX Minerals
MGX Minerals is a diversified Canadian resource and technology
company with interests in global advanced material, energy and
water assets. Learn more at www.mgxminerals.com.
Contact Information
Jared Lazerson President and CEO Telephone: 1.604.681.7735 Web:
www.mgxminerals.com
Neither the Canadian Securities Exchange nor its Regulation
Services Provider (as that term is defined in the policies of the
Canadian Securities Exchange) accepts responsibility for the
adequacy or accuracy of this release.
Forward-Looking Statements
This press release contains forward-looking information or
forward-looking statements (collectively "forward-looking
information") within the meaning of applicable securities laws.
Forward-looking information is typically identified by words such
as: "believe", "expect", "anticipate", "intend", "estimate",
"potentially" and similar expressions, or are those, which, by
their nature, refer to future events. The Company cautions
investors that any forward-looking information provided by the
Company is not a guarantee of future results or performance, and
that actual results may differ materially from those in
forward-looking information as a result of various factors. The
reader is referred to the Company's public filings for a more
complete discussion of such risk factors and their potential
effects which may be accessed through the Company's profile on
SEDAR at www.sedar.com.
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