MGX Minerals Announces Completion of Gasification Scoping Study for Petroleum Coke to Hydrogen with Vanadium, Nickel and...
21 Novembre 2018 - 2:00PM
InvestorsHub NewsWire
MGX Minerals Announces Completion of Gasification
Scoping Study for Petroleum Coke to Hydrogen with Vanadium, Nickel
and Cobalt Extraction
Vancouver, BC -- November 21, 2018 -- InvestorsHub
NewsWire -- MGX Minerals Inc. (“MGX” or the
“Company”) (CSE: XMG /
FKT: 1MG / OTCQB: MGXMF)
and
Highbury Energy Inc. (“Highbury”) are pleased to
report completion of a comprehensive study analyzing
beneficial gasification routes from Petroleum Coke (“Petcoke”) to
three products of value: Hydrogen, FT Liquids and Fuel Gas. Each of
these products has potential markets in the oil sands and heavy oil
industry. The
report outlines a variety and comparison of plant design parameters
and a Petcoke-to-Hydrogen process with metals concentration via
gasification, utilizing Highbury’s patented dual-bed gasification
technology, which requires no fine grinding or air separation
unit. The goal of ongoing joint research with Highbury is to
develop fuel source alternatives and concentrated battery metals
by-products including vanadium, nickel and cobalt, which can be
seamlessly integrated into existing refinery operations. The
study is viewed as positive and the project will now move to the
demonstration plant design phase and preliminary pre-feasibility
analysis.
Metals in Pet Coke
and Ash
Previously released assay results of Petcoke
samples collected from stockpiles produced from the Fort McMurray
area mining and upgrading operation as well as an Edmonton refinery
are summarized below. Both samples originated from Delayed Coking
operations. Samples were obtained and prepared by Highbury and
metal contents analyzed by Acme
Labs of Vancouver, British Columbia using standard ICP
analyses.
Ash
Content
Ash content was determined by weighing residues
after burning coke samples of about 200 g in air in a muffle oven
over extended periods at 815°C. Table A indicates the average ash
content of 6 to 7 samples of each
coke.
Table A. Ash Content of Coke
Samples
Sample
name |
Ash content (%
wt.) |
No. of samples
tested |
Upgrader Coke A |
2.73 ±0.09 |
6 |
Refinery Coke B |
0.32 ±0.04 |
7 |
Upgrader Coke A had about nine times as much ash as
was in Refinery Coke
B.
Proximate
Analyses
The cokes contain over 95 % organic (non-mineral)
matter. Thermogravimetric analyses on 10 mg quantities are shown
below.
Table B. Proximate Analyses of Coke by the
Thermo-gravimetric Analyser
Method
Quantity (wt.
%) |
Upgrader Coke
A |
Refinery Coke
B |
Volatile Matter |
8.9 |
10.0 |
Fixed Carbon |
86.9 |
86.3 |
Residues |
4.3 |
1.7 |
Residue refers to
residual mineral matter left after the thermo-gravimetric test.
Except for the % Residue, the two cokes have similar combustion
properties.
Metals Analysis in
the Coke Samples
Lithium borate fusion ICP-MS method measures 45
trace metal concentrations in the coke. Results are expressed
as (mg/kg) or ppmwt. Table C lists concentrations of selected
metals.
Table C. Selected Metal Concentrations in
Coke (mg Metal/kg Coke)
Sample |
V |
Ni |
Cu |
Zr |
Co |
Au |
Ag |
Upgrader Coke A |
421 |
76.8 |
86.2 |
40.5 |
4.8 |
0.0011 |
< 0.1 |
Refinery Coke B |
458 |
53.4 |
35.9 |
1.3 |
1.3 |
<0.0005 |
<0.1 |
Vanadium is the highest concentration of the 45
trace metals detected in the coke
samples.
Ash
Analyses
Ash analysis was completed by Bureau Veritas
Commodities Canada Ltd. (“BV”) of Vancouver, British Columbia using
XRF method (XF701). Results are expressed as % wt. in the ash as
oxide. Sixteen elements as oxides, and LOI (loss on ignition)
are determined. The ash samples were prepared in Highbury’s
laboratory and sent to BV for analysis. The maximum % the analysis
method could accommodate was 10.0 % for V2O5;
therefore ash samples were diluted by mixing with other solids. In
the Highbury laboratory both Al2O3 and
Fe2O3 were
used.
Table D. Selected Species in the Ash of
Each Coke Type
Species (wt.
%) |
Upgrader Coke Ash
A |
Refinery Coke Ash
B |
Al2O3 |
27.7 |
9.8 |
SiO2 |
42.6 |
23.6 |
V2O5 |
6.6 |
45.1 |
Fe2O3 |
8.0 |
2.7 |
TiO2 |
5.7 |
0.7 |
K2O+MgO+CaO |
4.0 |
6.4 |
LOI |
0.0 |
4.3 |
SubTotal (wt.%) |
90.8 |
92.5 |
For Upgrader Coke A, the sum of
Al2O3 +SiO2 is about 70 %.
V2O5 is about 6.6%, according to the ash
analyses. For Refinery Coke B, the average %
V2O5 in the ash is 45
%.
Table E. Trace Metals Concentration in Ash
(mg Metal/kg Ash) for Selected Species [Two Determinations
Average]
Sample |
V |
Ni |
Cu |
Zr |
Co |
Au |
Ag |
Mo |
Upgrader Coke Ash
A |
34600 |
740 |
130 |
1840 |
230 |
0.02 |
2.5 |
1405 |
Refinery Coke Ash
B |
193000 |
177000 |
340 |
405 |
620 |
0.02 |
0.175 |
5000 |
Vanadium metal concentrations are 3.5 % wt. in
Upgrader Coke Ash A, and 19.3 % wt. in Refinery Coke Ash B, which
is also enriched in Nickel.
Background
Petcoke is a carbon material by-product of the oil
and gas industry that forms during the oil refining process. As
refineries have become more efficient at processing extra heavy
crude oils (bitumen) over the last two decades, output of petcoke
globally has risen significantly. Because petcoke originates from
heavier petroleum fractions, its denser impurities such as metals
and sulphur compounds are concentrate in
it.
The majority of Canadian petcoke output occurs in
close proximity to oil sand producing regions, where bitumen is
upgraded into synthetic crude oil. Specifically, the Province of
Alberta is known to host vast stockpiles of petcoke. According to
the Alberta Energy Regulator, petcoke inventories are estimated to
have reached 106 million tonnes in
2016(1).
(1) Source: Alberta Energy Industry,
Alberta Mineable Oil Sands Plant
Statistics
Research and
Development
Development of the detailed process will be
spearheaded by Dr. Paul Watkinson, a Professor Emeritus in the
Department of Chemical and Biological Engineering at the University
of British Columbia and a co-founder of Highbury. Dr. Watkinson is
a published expert in the field of gasification and oversaw early
work on related oil sand gasification in the early 1990’s. He is
also a registered Professional Engineer, Fellow of the Chemical
Institute of Canada and Fellow of the Canadian Academy of
Engineering. Dr. Watkinson is also an active participant in the
Canadian Society for Chemical Engineering as well as Engineering
Conferences International. He has received numerous awards for his
research and has published multiple articles in scientific journals
on pilot-scale investigations of conversion of carbonaceous solids,
such as coal, shale and biomass, into gaseous and liquid
fuels.
N.I.
43-101
Although authored by leading experts in the field
and significantly advancing research and development of
gasification and metals extraction, N.I. 43-101 does not recognize
a scoping study as a N.I. 43-101 Compliant Report. As such MGX
cannot release any economic projections whatsoever in regard to
metals extraction or associated gasification steps. As
Petcoke is widely available in very large quantities at low cost in
the Alberta Oil Sands it is unlikely MGX will complete an N.I.
43-101 Resource Estimate, which precludes a compliant Preliminary
Economic Assessment, Pre-feasibility Study or Feasibility Study
that would allow for the release of economic projections. It is
anticipated that a Pre-feasibility and Feasibility Study will be
completed for the plant design itself but not the Petcoke resource
as it will be purchased as needed and not owned or controlled by
MGX.
Qualified
Person
Andris Kikauka (P. Geo.), Vice President of
Exploration for MGX Minerals, has reviewed and approved the
technical information in this press release. Mr. Kikauka is a
non-independent Qualified Person within the meaning of National
Instrument 43-101 Standards.
About Highbury
Energy
Highbury Energy Inc. is an innovative energy
company dedicated to the development and utilization of renewable
energy resources through the procurement and conversion of biomass.
Highbury has developed a proprietary dual-bed steam gasification
technology and patented gas cleanup system that converts biomass
into high-grade synthesis or fuel gas. This robust process produces
a medium calorific value gas from most types of organic matter,
such as wood or agricultural wastes, without need of tonnage
oxygen. The cleaned synthesis gas can readily replace natural gas
in industrial kilns and furnaces in the mineral, pulp & paper,
glass, and cement industries. Alternately, the syngas can fuel an
internal combustion engine to make electricity, with waste heat
used for refrigeration, or district heating. Syngas can also
be converted to high value low carbon liquid fuels such as diesel
or jet fuel, or into chemicals such as methanol or
ethanol.
About MGX
Minerals
MGX Minerals is a diversified Canadian resource and
technology company with interests in global advanced material,
energy and water assets. Learn more at www.mgxminerals.com.
Contact
Information
Jared Lazerson
President and CEO
Telephone: 1.604.681.7735
Web: www.mgxminerals.com
Neither the Canadian Securities Exchange nor its
Regulation Services Provider (as that term is defined in the
policies of the Canadian Securities Exchange) accepts
responsibility for the adequacy or accuracy of this
release.
Forward-Looking
Statements
This press release contains forward-looking
information or forward-looking statements (collectively
"forward-looking information") within the meaning of applicable
securities laws. Forward-looking information is typically
identified by words such as: "believe", "expect", "anticipate",
"intend", "estimate", "potentially" and similar expressions, or are
those, which, by their nature, refer to future events. The Company
cautions investors that any forward-looking information provided by
the Company is not a guarantee of future results or performance,
and that actual results may differ materially from those in
forward-looking information as a result of various factors. The
reader is referred to the Company's public filings for a more
complete discussion of such risk factors and their potential
effects which may be accessed through the Company's profile on
SEDAR at www.sedar.com.
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